Highly efficient dye-sensitized solar cell prepared by electrophoretic deposition method: the effect of TiO<Subscript>2</Subscript> films thickness on the performance of cells

In this work, nanocrystalline P25 TiO₂ films with different thicknesses were deposited on FTO coated glass substrates by an electrophoretic deposition technique (EPD) and applied as the work electrode for dye-sensitized solar cells (DSSC) using cis-bis(isothiocyanato)(2,2'-bipyridyl-4,4'-dicarboxylato)(4,4'di-nonyl-2'-bipyridyl) ruthenium(II) (Z907, Dyesol) as sensitizing dye.The results showed that the increasing the thickness of TiO₂ films lead to increase the adsorption of the dye on the TiO₂ layers which in turns improved the short-circuit photocurrent (J_sc) and open-circuit voltage (V_oc), respectively. Furthermore, it was found that the effects of the surface states on the recombination of the photo-injected electrons (electron–hole pairs) in the TiO₂ films strongly depend on theTiO₂ electrode annealing temperature. Finally, a DSSC with a 32.82 μm thickness for TiO₂ film annealed at 600°C produced the highest conversion efficiency with an incident solar energy of 100 mW/cm² (η = 8.23%, J_sc = 15.98, V_oc = 0.73, FF = 0.7).     

A spread-sheet model for efficient production and scheduling of a manufacturing line/cell

In this paper we develop an efficient spread-sheet production planning/scheduling model for a resource-constraint production line or a manufacturing cell that produces several products but one at a time with significant changeover time and changeover cost. There are also management and physical constraints related to the operating hours, production capacity and amount of inventory allowed. The production line/cell supplies several products to customers who pull the products according to their own operating policy (working hours) that may be different from manufacture's operating hours. We also show several real-world applications and highlight the benefits and merits of the model.     

Synthesis and characterization of antibacterial polyurethane coatings from quaternary ammonium salts functionalized soybean oil based polyols

In this study, a simple and versatile synthetic approach was developed to prepare bactericidal polyurethane coatings. For this purpose, introduction of both quaternary ammonium salts (QASs), with well-known antibacterial activity, and reactive hydroxyl groups on to the backbone of soybean oil was considered. Epoxidized soybean oil was reacted with diethylamine and the intermediate tertiary amine containing polyol was reacted with two different alkylating agents, methyl iodide and benzyl chloride, to produce MQAP and BQAP, respectively. These functional polyols were reacted with different diisocyanate monomers to prepare polyurethane coatings. Depending on the structure of monomers used for the preparation of polyurethane coatings, initial modulus, tensile strength and elongation at break of samples were in the ranges of 122–339 MPa, 4.6–12.4 MPa and 8.4–46%, respectively. Polyurethane coatings based on isophorone diisocyanate showed proper mechanical properties and adhesion strength (0.41 MPa) for coating application. Study of fibroblast cells interaction with prepared polyurethanes showed promising cells viability in the range of 78-108%. Meanwhile, MQAP based samples with higher concentration of QASs showed better adhesion strength, surface hydrophilicity and antibacterial activity (about 95% bacterial reduction). Therefore, these materials can find applications as bactericidal coating for biomedical devices and implants.     

A Molecular Dynamics Study of Description Models for Shear Viscosity in Nanochannels: Mixtures and Effect of Temperature

Equilibrium molecular dynamics simulation was utilized to calculate the shear viscosity of monoatomic molecules liquid flow confined in a nanochannel in the pure state and their binary mixtures. The pure flow viscosity data of argon, krypton, and xenon were used to predict their binary mixture viscosities using prediction methods proposed in the literature. Each method was evaluated by comparison of its results with those obtained by validated molecular dynamics simulation at different temperatures. In addition, correlative methods for mixture viscosity estimation and temperature dependence models were evaluated and corresponding model parameters were obtained. Moreover, the relations representing mixture parameter values as a function of the pure ones were determined and evaluated according to their accuracy.     

Bipotential deposition of nickel–cobalt hexacyanoferrate nanostructure on graphene coated stainless steel for supercapacitors

Graphene oxide (GO) was deposited on inexpensive and mechanically stable stainless steel (SS) electrode by electrophoretic deposition (EPD) technique. GO was reduced electrochemically in NaNO₃ to obtain electrochemically reduced graphene oxide (ERGO). Next, Hybrid nickel–cobalt hexacyanofarrate (NiCoHCF) nanoparticles were deposited from solution containing Ni⁺² and Co⁺² with ratio of 1:1 on ERGO/SS by bipotential method. Morphological investigation of prepared sample by scanning electron microscopy showed the presence of nanoparticles with diameters in the range of 15–50 nm. Crystal structure of nanocomposite was investigated by X-ray diffraction technique. Electrochemical behavior of prepared film indicates that hybrid nanocomposite has higher specific capacitance (411 F g⁻¹) than ERGO (185.2 F g⁻¹) in KNO₃ solution at current density of 0.2 A g⁻¹. In other words, pseudocapacitor that is formed based on the faradaic behavior of NiCoHCF can improve the capacitive performance of ERGO.     

Antioxidant and Antihemolytic Activities of Ethanolic Extract of Flowers,Leaves, and Stems of Hyssopus officinalis L. Var. angustifolius

In this study, antioxidant and antihemolytic activities of ethanolic extract of flowers, leaves, and stems of Hyssopus officinalis L. Var. angustifolius were investigated employing different in vitro assay systems. Extracts showed good antioxidant activity. IC₅₀ for 1,1-diphenyl-2-picryl hydrazyl radical-scavenging activity were 148.8 ± 4.31 μg mL^?1 for flowers, 79.9 ± 2.63 μg mL^?1 for stems, and 208.2 ± 6.45 μg mL^?1 for leaves. All extracts showed moderate iron (II) chelating ability. Extracts exhibited good antioxidant activity in the hemoglobin-induced linoleic acid model and also they were capable of scavenging hydrogen peroxide in a concentration dependent manner. Extracts showed good antihemolytic activity againts hydrogen peroxide-induced hemolysis (IC₅₀ were 48.51 ± 2.27 μg mL^?1 for flowers, 19.47 ± 0.73 μg mL^?1 for leaves, and 63.1 ± 2.65 μg mL^?1 for stems). The total amount of phenolic compounds in the extracts was determined as gallic acid equivalents and total flavonoid content was calculated as quercetin equivalents from a calibration curve.     

New resistorless and electronically tunable realization of dual-output VM all-pass filter using VDIBA

In this paper, a new active element called voltage differencing inverting buffered amplifier (VDIBA) is presented. Using single VDIBA and a capacitor, a new resistorless voltage-mode (VM) first-order all-pass filter (APF) is proposed, which provides both inverting and non-inverting outputs at the same configuration simultaneously. The pole frequency of the filter can be electronically controlled by means of bias current of the internal transconductance. No component-matching conditions are required and it has low sensitivity. In addition, the parasitic and loading effects are also investigated. By connecting two newly introduced APFs in open loop a novel second-order APF is proposed. As another application, the proposed VM APF is connected in cascade to a lossy integrator in a closed loop to design a four-phase quadrature oscillator. The theoretical results are verified by SPICE simulations using TSMC 0.18 μm level-7 CMOS process parameters with ±0.9 V supply voltages. Moreover, the behavior of the proposed VM APF was also experimentally measured using commercially available integrated circuit OPA860 by Texas Instruments.     

New current-mode current-controlled universal filter with single input and three outputs

In this study, a new current-mode current-controlled universal filter with single input and three outputs is presented. The proposed circuit uses single-output current controlled conveyors (CCCIIs) and can simultaneously realize lowpass, bandpass and highpass filter functions all at high impedance outputs. Realization of notch and allpass responses does not require additional active elements. The circuit enjoys independent current-control of the parameters ω₀ and ω₀/Q without disturbing the gains of the lowpass, bandpass and highpass filters. Both its active and passive sensitivities are low.     

Arbitrary dual-band unequal Wilkinson power divider based on negative refractive index transmission lines

This paper focused on the application of negative refractive index transmission line (NRI-TL) in dual-band unequal Wilkinson power divider (WPD) with controllable frequency and power dividing ratio. Theory and design procedure of the dual-band NRI-TL are presented in details. For demonstration, two dual-band unequal Wilkinson power dividers (WPDs) with power dividing ratio of 2 : 1 and operating frequencies of 0.9 and 1.8 GHz are designed, fabricated and tested. The first unequal divider is based on 2-stage NRI-TLs and the second one is based on 4-stage NRI-TLs. In addition, these two types of NRI-TLs are presented to demonstrate that by increasing the number of NRI-TL unit-cells the phase response of the NRI-TLs converge to the desired characteristic. The good agreement between measured and simulated results confirmed the design concept and derived closed-form design equations. Measurements show that the first divider has 18.37% and 21.86% relative bandwidths and the second one has 33.52% and 29.12% relative bandwidths at 0.9 and 1.8 GHz, respectively. The design concept of this paper can be extended to equal dual-band power dividers with arbitrary frequency ratio.     

Polyol-Derived Alkoxide/Hydroxide Base Catalysts II: Transesterification Reactions

Biodiesel, fatty acid methyl ester (FAME), was produced by transesterification of canola oil with methanol in the presence of a series of alkoxide/hydroxide base catalysts produced from glycerol, 1,2-propanediol, 1,3-propanediol, xylitol, or sorbitol produced by dehydration reaction of sodium hydroxide in the presence of polyols. Transesterification reactions proceeded efficiently in the presence of sodium alkoxide catalysts prepared at three different mole ratios of sodium hydroxide to glycerol (1:1, 2:1, and 3:1). The production of methyl ester during the course of the reaction was determined repeatedly and the reaction progress was compared with that achieved in a reaction catalyzed by freshly prepared anhydrous sodium methoxide as a standard catalyst. Sodium alkoxide/hydroxide catalysts activity during the first 2 min of the reaction was in the order of: sorbitol < xylitol < sodium methoxide < 1,2-propanediol < 1,3-propanediol < glycerol regardless of the mole ratio of sodium hydroxide to glycerol. All catalysts showed a higher methyl ester accumulation at higher ratios of sodium hydroxide to polyol and had the following order 1:1 < 2:1 < 3:1 (sodium hydroxide:glycerol). Several of these catalysts were as powerful as sodium methoxide in catalyzing the transesterification reaction at the same mole concentration. All alkoxide/hydroxide catalysts resulted in a high FAME accumulation (>95 wt%) in a single transesterification batch reaction.